Abstract
Homopolymer hydrogel of 2-acrylamido-2-methylpropane sulfonic acid (AMPS) and its nanocomposite counterpart were prepared to study their swelling properties. The hydrogels showed ability to absorb and retain electrolytes as well as binary mixtures of water and organic solvents (i.e., methanol, ethanol, acetone, ethylene glycol (EG), polyethylene glycol, N-methyl-2-pyrrolidone (NMP), and dimethylsulfoxide (DMSO). The nanocomposite gel exhibited lower swelling in all solvent compositions in comparison with non-composite gel. Unlike conventional acrylic acid-based hydrogels, the poly(AMPS) gels showed superabsorbing capacity in pure ethanol, methanol, EG, DMSO and NMP. Meanwhile, swelling capacity of poly(AMPS) hydrogel in DMSO-water mixtures was surprisingly found to be even higher than that in water. This extraordinary superswelling behavior was explained based on the interactions involved in solvation as well as the solubility parameters. The gels showed pH-independent superabsorbency in a wide range of pH (3–11). Saline-induced swelling transitions were also investigated and the ionic interactions were confirmed by FTIR spectroscopy.
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References
Buchholz FL, Graham AT (1998) Modern superabsorbent polymer technology. Wiley-VCH, New York Chap. 1–7
Brannon-Peppas L, Harland RS (1990) Absorbent polymer technology. Elsevier, Amsterdam Chap. 1–4
Andrade JD (1976) Hydrogels for medical and related applications, ACS symp. Series, 31. American Chemical Society, Washington DC, p 1
Po R (1994) J Macromol Sci- Rev Macromol Chem Phys C34:607
Buchholz FL, Peppas NA (1994) Superabsorbent polymers science and technology, ACS symposium Series, 573. American Chemical society, Washington, DC Chap. 2, 7, 8 and 9
Zohuriaan-Mehr MJ, Kabiri K (2008) Iran. Polym J 17:451
Lee WF, Chen YC (2004) J Appl Polym Sci 91:2934. doi:10.1002/app.13499
Lee WF, Jou LL (2004) J Appl Polym Sci 94:74. doi:10.1002/app.20730
Lee WF, Fu YT (2003) J Appl Polym Sci 89:3652. doi:10.1002/app.12624
Lee WF, Yang LG (2004) J Appl Polym Sci 92:3422. doi:10.1002/app.20370
Yissar VP, Andrew RG, Shipway N, Bourekno T, Willner I (2001) Adv Mater 13:1320. doi:10.1002/1521-4095(200109)13:17<1320::AID-ADMA1320>3.0.CO;2-8
Kim JH, Lee TR (2004) Chem Mater 16:3647. doi:10.1021/cm049764u
Chen W, Yuan Y, Yan L (2000) Mater Res Bull 35:807. doi:10.1016/S0025-5408(00)00266-X
Tanaka T (1979) Polymer (Guildf) 20:1404. doi:10.1016/0032-3861(79)90281-7
Li A, Wang A, Chen J (2004) J Appl Polym Sci 94:1869. doi:10.1002/app.20850
Caykara T, Dogmus M (2004) Eur Polym J 40:2605. doi:10.1016/j.eurpolymj.2004.06.024
Nisha CK, Dhara D, Chatterji PR (2000) J. Macromol Sci-Pure Appl Chem A37:1447. doi:10.1081/MA-100101164
Kiritoshi Y, Ishihara K (2003) Sci Technol Adv Mater 4:93. doi:10.1016/S1468-6996(03)00010-X
Richter A, Howitz S, Kuckling D, Arndt KF (2004) Sens Actuators B99:451
Muta H, Kawauchi S, Satoh M (2003) Colloid Polym Sci 282:149. doi:10.1007/s00396-003-0922-1
Muta H, Miwa M, Satoh M (2001) Polymer (Guildf) 42:6313. doi:10.1016/S0032-3861(01)00098-2
Muta H, Ishida K, Tamaki E, Satoh M (2002) Polymer (Guildf) 43:103. doi:10.1016/S0032-3861(01)00611-5
Yasumoto N, Hata Y, Satoh M (2004) Polym Int 53:766. doi:10.1002/pi.1443
Nishiyama Y, Satoh M (2000) J Polym Sci Part B. Polym Phys 38:2791. doi:10.1002/1099-0488(20001101)38:21<2791::AID-POLB80>3.0.CO;2-1
Fukunaga Y, Hayashi M, Satoh M (2007) J Polym Sci Part B. Polym Phys 45:1166. doi:10.1002/polb.21141
Haraguchi K, Takehisa T (2002) Adv Mater 14:1120. doi:10.1002/1521-4095(20020816)14:16<1120::AID-ADMA1120>3.0.CO;2-9
Lee WF, Chen YC (2006) Eur Polym J 42:1634. doi:10.1016/j.eurpolymj.2006.01.014
Durmaz S, Okay O (2000) Polymer (Guildf) 41:3693. doi:10.1016/S0032-3861(99)00558-3
Murat M, Okay O (2005) Polymer (Guildf) 46:8119. doi:10.1016/j.polymer.2005.06.102
Wang KH, Choi MH, Koo CM, Choi YS, Chung IJ (2001) Polymer (Guildf) 42:9819. doi:10.1016/S0032-3861(01)00509-2
El-Hag AA, Abd El Rehim HA, Hegazy EA, Ghobashy MM (2006) Radiat Phys Chem 75:1041. doi:10.1016/j.radphyschem.2005.05.022
Kabiri K, Mirzadeh H, Zohuriaan-Mehr MJ (2008) J Appl Polym Sci (submitted).
Kabiri K, Mirzadeh H, Zohuriaan-Mehr MJ (2008) J Appl Polym Sci 110:3420. doi:10.1002/app.28148
Kabiri K, Mirzadeh H, Zohuriaan-Mehr MJ (2007) Iran. Polym J 16:147
Rodehed C, Ranby B (1986) Polymer (Guildf) 27:313. doi:10.1016/0032-3861(86)90346-0
Chen J, Shen J (2000) J Appl Polym Sci 75:1331. doi:10.1002/(SICI)1097-4628(20000314)75:11<1331::AID-APP2>3.0.CO;2-R
Çaykara U, Özyürek C, Kantolu Ö, Güven O (2002) J Polym Sci Part Polym Chem 40:1995
Zohuriaan-Mehr MJ, Motazedi Z, Kabiri K, Ershad-Langroudi A, Allahdadi I (2006) J Appl Polym Sci 102:5667. doi:10.1002/app.25033
Champ S, Xue W, Huglin MB (2000) Macromol Chem Phys 201:931. doi:10.1002/1521-3935(20000601)201:9<931::AID-MACP931>3.0.CO;2-#
Tong Z, Liu X (1994) Macromolecules 27:844. doi:10.1021/ma00081a033
Vaisman II, Berkowitz ML (1992) J Am Chem Soc 114:7889. doi:10.1021/ja00046a038
Kirchner B, Reiher M (2002) J Am Chem Soc 124:6206. doi:10.1021/ja017703g
Shin DN, Wijnen JW, Engberts JBFN, Wakisaka A (2001) J Phys Chem B 105:6759. doi:10.1021/jp0111517
Krishner B, Hutter J (2002) Chem Phys Lett 364:497. doi:10.1016/S0009-2614(02)01377-5
Alia JM, Edwards HGM, Kiernan BM (2004) Spectrochemica Acta Part A 60:1533. doi:10.1016/j.saa.2003.08.016
Grulke EA (1999) In: Brandrup J, Immergut EH, Grulke EA (eds) Polymer handbook, 4th edn. Wiley, New York, pp VII/675–VII/697
Scild HG, Muthkumar M, Tirrell DA (1991) Macromolecules 24:948. doi:10.1021/ma00004a022
Atta AM (2002) Polym Adv Technol 13:567. doi:10.1002/pat.226
Atta AM, Arndt KF (2001) Polym Int 50:1360. doi:10.1002/pi.790
Vasheghani-Farahani E, Vera JH, Cooper DG, Weber ME (1990) Ind Eng Chem Res 29:554. doi:10.1021/ie00100a010
Qi X, Liu M, Chen Z, Liang R (2007) Polym Adv Technol 18:184. doi:10.1002/pat.847
Horkay F, Tasaki I, Basser PJ (2000) Biomacromolecules 1:84. doi:10.1021/bm9905031
Kabiri K, Faraji-Dana S, Zohuriaan-Mehr MJ (2005) Polym Adv Technol 16:659. doi:10.1002/pat.637
Kiatkamjornwong S, Phunchareon P (1999) J Appl Polym Sci 72:1349. doi:10.1002/(SICI)1097-4628(19990606)72:10<1349::AID-APP16>3.0.CO;2-K
Zhang C, Easteal AJ (2003) J Appl Polym Sci 88:2563. doi:10.1002/app.12095
Velada JL, Liu Y, Huglin MB (1998) Macromol Chem Phys 199:1127. doi:10.1002/(SICI)1521-3935(19980601)199:6<1127::AID-MACP1127>3.0.CO;2-9
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Kabiri, K., Zohuriaan-Mehr, M.J., Mirzadeh, H. et al. Solvent-, ion- and pH-specific swelling of poly(2-acrylamido-2-methylpropane sulfonic acid) superabsorbing gels. J Polym Res 17, 203–212 (2010). https://doi.org/10.1007/s10965-009-9306-7
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DOI: https://doi.org/10.1007/s10965-009-9306-7